Murray State's Digital Commons - Scholars Week: Thiol-ene poly(ionic liquid) networks for ion transport and carbon dioxide absorption
 

Honors College Senior Thesis Presentations

Thiol-ene poly(ionic liquid) networks for ion transport and carbon dioxide absorption

Presenter Information

Abbigail LeachFollow

Academic Level at Time of Presentation

Senior

Major

Biology Pre-Med

Minor

Chemistry and Spanish

List all Project Mentors & Advisor(s)

Kevin Miller

Presentation Format

Oral Presentation

Abstract/Description

Ionic liquids have been shown to have dynamic thermal and conductive properties making them favorable for use in a variety of ways. Previous work in the Miller Lab has shown that thiol-ene polymerization is an effective way to click unsaturated bonds to thiol groups using photopolymerization. By using different chain lengths, varying ratio of monomer to thiol, and adding a different amounts of free ionic liquid, we are able to manipulate the properties of these materials. This project looks at the difference in thermal, mechanical, and conductive properties in 8 different films, all varying from one another in chain length, ratio, or amount of free ionic liquid present. All 8 films have undergone the same mechanical, thermal, and conductive testing in order to effectively compare the results between the various films. Some of the materials have also undergone carbon dioxide testing via a quartz crystal microbalance (QCM) to analyze their ability to absorb carbon dioxide. Compounds that effectively absorb carbon dioxide, may have the potential to be used in some kind of carbon dioxide sensor or in other applications involving carbon dioxide. Through analysis of these different films, we will be able to determine which conditions are the most optimal for the stability of these materials.

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Thiol-ene poly(ionic liquid) networks for ion transport and carbon dioxide absorption

Ionic liquids have been shown to have dynamic thermal and conductive properties making them favorable for use in a variety of ways. Previous work in the Miller Lab has shown that thiol-ene polymerization is an effective way to click unsaturated bonds to thiol groups using photopolymerization. By using different chain lengths, varying ratio of monomer to thiol, and adding a different amounts of free ionic liquid, we are able to manipulate the properties of these materials. This project looks at the difference in thermal, mechanical, and conductive properties in 8 different films, all varying from one another in chain length, ratio, or amount of free ionic liquid present. All 8 films have undergone the same mechanical, thermal, and conductive testing in order to effectively compare the results between the various films. Some of the materials have also undergone carbon dioxide testing via a quartz crystal microbalance (QCM) to analyze their ability to absorb carbon dioxide. Compounds that effectively absorb carbon dioxide, may have the potential to be used in some kind of carbon dioxide sensor or in other applications involving carbon dioxide. Through analysis of these different films, we will be able to determine which conditions are the most optimal for the stability of these materials.